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Vibronic Interactions in Molecules and Crystals by Isaac B. Bersuker (English) P

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Specificaties

Objectstaat
Nieuw: Een nieuw, ongelezen en ongebruikt boek in perfecte staat waarin geen bladzijden ontbreken of ...
ISBN-13
9783642834813
Book Title
Vibronic Interactions in Molecules and Crystals
ISBN
9783642834813
Publication Name
Vibronic Interactions in Molecules and Crystals
Item Length
9.3in
Publisher
Springer Berlin / Heidelberg
Publication Year
2011
Series
Springer Series in Chemical Physics Ser.
Type
Textbook
Format
Trade Paperback
Language
English
Item Height
0.4in
Author
Isaac B. Bersuker, Victor Z. Polinger
Item Width
6.1in
Item Weight
23.4 Oz
Number of Pages
Xii, 422 Pages

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Product Information

Vibronic interaction effects constitute a new field of investigation in the physics and chemistry of molecules and crystals that combines all the phenomena and laws originating from the mixing of different electronic states by nuclear displacements. This field is based on a new concept which goes beyond the separate descriptions of electronic and nuclear motions in the adiabatic approximation. Publications on this topic often appear under the title of the lahn-Thller effect, although the area of application of the new approach is much wider: the term vibronic interaction seems to be more appropriate to the field as a whole. The present understanding of the subject was reached only recently, during the last quarter of a century. As a result of intensive development of the theory and experiment, it was shown that the nonadiabatic mixing of close-in-energy elec- tronic states under nuclear displacements and the back influence of the modified electronic structure on the nuclear dynamics result in a series of new effects in the properties of molecules and crystals. The applications of the theory of vibronic in- of spectroscopy including visible, ultraviolet, in- teractions cover the full range frared, Raman, EPR, NMR, nuclear quadrupole resonance (NQR), nuclear gam- ma resonance (NOR), photoelectron and x-ray spectroscopy], polarizability and magnetic susceptibility, scattering phenomena, ideal and impurity crystal physics and chemistry (including structural as well as ferroelectric phase transitions), stereochemistry and instability of molecular (including biological) systems, mechanisms of chemical reactions and catalysis.

Product Identifiers

Publisher
Springer Berlin / Heidelberg
ISBN-10
3642834817
ISBN-13
9783642834813
eBay Product ID (ePID)
143691233

Product Key Features

Author
Isaac B. Bersuker, Victor Z. Polinger
Publication Name
Vibronic Interactions in Molecules and Crystals
Format
Trade Paperback
Language
English
Publication Year
2011
Series
Springer Series in Chemical Physics Ser.
Type
Textbook
Number of Pages
Xii, 422 Pages

Dimensions

Item Length
9.3in
Item Height
0.4in
Item Width
6.1in
Item Weight
23.4 Oz

Additional Product Features

Series Volume Number
49
Number of Volumes
1 Vol.
Lc Classification Number
Qc170-197
Table of Content
1. Introduction.- 2. Vibronic Interactions and the Jahn-Teller Theorem.- 2.1 Adiabatic Approximation.- 2.2 The Vibronic Hamiltonian.- 2.3 The Jahn-Teller Theorem.- 3. Adiabatic Potentials.- 3.1 The Orbital Doublet (E Term).- 3.2 Symmetry of Jahn-Teller Systems.- 3.3 Triplet and Quadruplet Terms.- 3.4 Pseudodegenerate Electronic Terms (Pseudo-Jahn-Teller Effect).- 3.5 Adiabatic Potentials for Multimode Systems.- 3.6 The Jahn-Teller Effect in Polynuclear Clusters.- 4. Solution of Vibronic Equations. Tunneling Splitting.- 4.1 Weak Vibronic Coupling. Perturbation Theory.- 4.2 Strong Vibronic Coupling. Free Rotation of Distortions.- 4.3 Hindered Rotations and Pulse Motions of Distortions. Tunneling Splitting.- 4.4 Numerical Solutions of Vibronic Equations.- 4.5 Multiparticle Methods in the Theory of the Jahn-Teller Effect.- 4.6 The Multimode Jahn-Teller Effect. Phonon Dispersion in Crystals.- 4.7 Factors of Vibronic Reduction.- 5. Spectroscopic Manifestations of Vibronic Effects.- 5.1 The Shape of Optical Bands of Electron Transitions Between Degenerate Electronic Terms.- 5.2 Splitting of the Zero-Phonon Lines of the Optical Absorption and Luminescence.- 5.3 Vibronic Effects in Infrared Absorption and Raman Spectra.- 5.4 The Dynamic Jahn-Teller Effect in Magnetic Resonance Spectra.- 5.5 Electron Paramagnetic Resonance. The Static Jahn-Teller Effect.- 6. Cooperative Phenomena. Structural Phase Transitions.- 6.1 Ordering of Distortions in Crystals. Cooperative Jahn-Teller Effect.- 6.2 Pseudo-Jahn-Teller Mechanism of Spontaneous Polarization of Crystals. The Vibronic Theory of Ferroelectricity.- 6.3 The Vibronic Theory of Structural Transformations in CondensedMedia.- Appendix A. Expansion of the Full Vibrational Representation in Terms of Irreducible Ones.- Appendix B. Expansion of the Symmetric and Antisymmetric Products of Degenerate Representations.- Appendix C Proof of the Jahn-Teller Theorem.- References.
Copyright Date
1989
Topic
Physics / Crystallography, Physics / Atomic & Molecular, Physics / Nuclear
Dewey Decimal
539/.6
Intended Audience
Scholarly & Professional
Dewey Edition
19
Illustrated
Yes
Genre
Science

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